![(2<i>R</i>,2′<i>R</i>-(+)-[<i>N</i>,<i>N</i>′-Bis(2-pyridylmethyl)]-2,2′-bipyrrolidinebis(acetonitrile)iron(II) hexafluoroantimonate](https://www.sustainable-bio.com/green-chemistry/wp-content/themes/green-chemistry/images/nopic.png)
(2R,2′R-(+)-[N,N′-Bis(2-pyridylmethyl)]-2,2′-bipyrrolidinebis(acetonitrile)iron(II) hexafluoroantimonate
| Catalog Number: | TMC-034 |
| CAS Number: | 1361315-26-5 |
| Molecular Weight: | 931.90 g/mol |
| Description: | (2R,2′R-(+)-[N,N′-Bis(2-pyridylmethyl)]-2,2′-bipyrrolidinebis(acetonitrile)iron(II) hexafluoroantimonate is a chiral metal complex with a structure consisting of dipyridylmethyl and bipyrrolidine as ligands coordinated to the center of iron(II) and forming stable organometallic complexes with acetonitrile and hexafluoroantimonate roots. The compounds are usually applied in asymmetric catalytic reactions to induce selectivity and high efficiency of the reaction through their chiral structure, emphasizing the concept of green chemistry and reducing the burden on the environment. |
Basic Information
| MDL | MFCD16038114 |
| PubChem Substance ID | 329764650 |
| UNSPSC | 12161600 |
| NACRES | NA.22 |
| SMILES String | [Fe++].CC#N.CC#N.F[Sb-](F)(F)(F)(F)F.F[Sb-](F)(F)(F)(F)F.C1C[C@H]([C@H]2CCCN2Cc3ccccn3)N(C1)Cc4ccccn4 |
| InChI | 1S/C20H26N4.2C2H3N.12FH.Fe.2Sb/c1-3-11-21-17(7-1)15-23-13-5-9-19(23)20-10-6-14-24(20)16-18-8-2-4-12-22-18;2*1-2-3;;;;;;;;;;;;;;;/h1-4,7-8,11-12,19-20H,5-6,9-10,13-16H2;2*1H3;12*1H;;;/q;;;;;;;;;;;;;;;+2;2*+5/p-12/t19-,20-;;;;;;;;;;;;;;;;;/m1................./s1 |
| InChI Key | XUNWHBGEOCZDBX-QSKJABRXSA-B |
| Melting Point | 215-226°C |
| Detection Method | HPLC, IR |
| Form | Powder |
| Core | Iron |
| Specification | 500 mg, 1 g, 2 g, 5 g |
| Application | (2R,2′R-(+)-[N,N′-Bis(2-pyridylmethyl)]-2,2′-bipyrrolidinebis(acetonitrile)iron(II) hexafluoroantimonate can be used as a catalyst for greener ketone synthesis by selective C-H oxidation of methylenes. |
Storage
| Storage | Store at 2-8°C. |
GET IT!
CD BioSciences-GreenChemistry is a distinguished and expert company in the green chemistry sector. We offer advanced technical services and comprehensive solutions to ensure the most satisfactory outcomes for our clients.
Contact UsOur products and services are for research use only and cannot be used for any clinical purposes.