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Hydroxy(cyclooctadiene)rhodium(I) dimer

Catalog Number: TMC-051
CAS Number: 73468-85-6
Molecular Weight: 456.19 g/mol
Description: Hydroxy(cyclooctadiene)rhodium(I) dimer is a metal-organic compound formed from two rhodium(I) atoms bridged by a hydroxyl group and coordinated with a 1,5-cyclooctadiene ligand. Its unique structure provides a flexible coordination environment, enabling it to play an efficient catalytic role in organic synthesis, especially in hydrogenation, carbonylation and coupling reactions.
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Basic Information

MDL MFCD08457638
PubChem Substance ID 24884496
UNSPSC 12161600
NACRES NA.22
SMILES String O[Rh].O[Rh].C1CC=CCCC=C1.C2CC=CCCC=C2
InChI 1S/2C8H12.2H2O.2Rh/c2*1-2-4-6-8-7-5-3-1;;;;/h2*1-2,7-8H,3-6H2;2*1H2;;/q;;;;2*+1/p-2/b2*2-1-,8-7-;;;;
InChI Key IUAQXTGDGDIMOD-MIXQCLKLSA-L
Melting Point 199°C
Detection Method HPLC, IR
Purity 95%
Form Solid
Core Rhodium
Specification 250 mg, 1 g, 5 g, 10 g
Application Hydroxy(cyclooctadiene)rhodium(I) dimer can be used as a catalyst for oxygenative addition to terminal alkynes for a greener synthesis esters, amides, and carboxylic acids.

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