The Impact of Additives on the Energetic Parameters and Physicochemical Properties of Environmentally Friendly Biomass Pellets

The Impact of Additives on the Energetic Parameters and Physicochemical Properties of Environmentally Friendly Biomass Pellets

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Biomass pellets are a critical component in the transition to sustainable and renewable energy systems. These compacted organic fuels, primarily derived from agricultural residues, wood, and other plant materials, serve as viable alternatives to fossil fuels like coal. Biomass pellets are used in heating systems, power plants, and as biofuels for industrial processes. The increasing reliance on these renewable energy sources is largely driven by the need to reduce greenhouse gas emissions and mitigate climate change. However, to maximize the potential of biomass pellets, their energy efficiency must be enhanced, and this is where the role of additives comes into play.

Unprocessed and ground biomass samples: grape pomace (GP) and corn cob (CC).Fig 1. Biomass grape pomace (GP) and corn cob (CC) before and after grinding. (Gheorghe D., et al., 2024)

Biomass Feedstocks: Grape Pomace and Corn Cob

In the context of biomass pellet production, the raw materials selected are of utmost importance. Grape pomace, a by-product of the wine industry, and corn cobs, a residue from corn farming, are excellent candidates for biofuel production. Grape pomace contains seeds, skins, and stems, rich in sugars and organic material, making it an ideal biomass feedstock. Corn cobs, on the other hand, are primarily composed of cellulose, hemicellulose, and lignin, which provide good energy potential when processed into pellets.

Both these materials, while abundant, require processing to create fuel-efficient pellets. The process involves reducing the raw material to a uniform size, removing excess moisture, and ensuring proper binding to form solid, durable pellets that can burn efficiently.

Additives in Biomass Pellet Production: Improving Combustion and Physical Properties

The addition of specific substances, or additives, during the pelletization process plays a significant role in enhancing the combustion characteristics and overall quality of biomass pellets. Three key additives explored in this study—sawdust, starch, and waste rapeseed oil—have been found to improve various aspects of pellet performance, such as calorific value, moisture content, and ash production.

Sawdust: Enhancing Pellet Density and Durability

Sawdust is commonly used in biomass pellet production due to its availability, low cost, and ability to improve pellet quality. As a natural binder, sawdust increases the bulk density of the pellets, which is essential for efficient storage and transport. Higher density pellets are also more durable, reducing the risk of degradation during handling. Moreover, sawdust helps to reduce the moisture content of pellets, making them more suitable for combustion, as high moisture can significantly hinder ignition and combustion efficiency.

Starch: Improving Pellet Strength and Reducing Moisture

Starch, a natural adhesive, is another popular additive used in biomass pellet production. When mixed with raw biomass, starch improves the mechanical strength of the pellets, ensuring that they remain intact during transport and storage. This adhesive property also helps reduce moisture content, further enhancing the combustion efficiency. However, the addition of starch should be carefully controlled, as excessive starch can reduce the calorific value of the pellets.

Waste Rapeseed Oil: Boosting Calorific Value and Combustion Efficiency

Waste rapeseed oil has emerged as a highly effective additive in biomass pellet production, primarily due to its high calorific content. When added to grape pomace and corn cob pellets, waste rapeseed oil significantly increases the energy density of the pellets. This enhancement is particularly valuable in applications where high-energy output is needed. In addition to improving the calorific value, waste rapeseed oil helps reduce the moisture content of the pellets and lowers ash generation during combustion, making it a highly beneficial additive for sustainable biofuel production.

The Impact of Additives on Combustion Properties

The combustion efficiency of biomass pellets is influenced by several factors, including moisture content, ash content, and the volatile matter present. Each of these factors plays a critical role in the performance of the pellets during combustion and in their environmental impact.

  • Moisture Content: A Key Factor in Combustion Efficiency
    Moisture content is one of the most significant parameters affecting the combustion properties of biomass pellets. High moisture levels necessitate more energy to evaporate the water before the fuel can burn, reducing the overall energy efficiency. In this study, it was found that the addition of waste rapeseed oil to grape pomace and corn cob pellets resulted in a substantial reduction in moisture content. Pellets with 10% waste rapeseed oil had moisture content as low as 2.81%, which is within the ideal range for efficient combustion. Reducing moisture content is essential for improving the ignition time and combustion efficiency of biomass pellets.
  • Ash Content: Reducing Operational Challenges
    Ash content is another critical parameter that affects the quality of biomass pellets. High ash content can lead to several operational challenges, including increased maintenance requirements for combustion systems, reduced heating efficiency, and the risk of slag formation during combustion. Pellets made with waste rapeseed oil exhibited significantly lower ash content, which contributes to cleaner burning and longer intervals between ash removal in heating systems. In the case of grape pomace pellets containing 10% waste rapeseed oil, the ash content was reduced to just 0.77%, demonstrating the effectiveness of oil as an additive in reducing the formation of solid waste during combustion.
  • Volatile Matter: Impact on Combustion and Emissions
    Volatile matter in biomass pellets refers to the compounds that are released during combustion, including gases like CO2, CO, and methane. A higher volatile content can result in incomplete combustion, leading to energy losses and increased emissions. Corn cob pellets without additives had a volatile matter content of 89.6%, which required more energy to burn before the thermal energy could be released. However, the addition of starch reduced the volatile content, thereby improving the combustion efficiency. This reduction in volatile matter also helps decrease the production of harmful gases, contributing to cleaner combustion.

Calorific Value and Energy Density: Measuring Pellet Performance

The calorific value of biomass pellets is a critical factor in determining their suitability as a biofuel. Pellets with higher calorific values release more energy when burned, making them more efficient for heating and power generation. In this study, the addition of waste rapeseed oil led to a marked increase in the calorific value of both grape pomace and corn cob pellets. Grape pomace pellets with 10% waste rapeseed oil achieved a calorific value of 22.14 MJ/kg, while corn cob pellets increased from 17.29 MJ/kg to 19.76 MJ/kg. These values demonstrate the positive impact of waste rapeseed oil on pellet energy content.

Energy Density: A Critical Measure for Storage and Transport

Energy density, which is a product of bulk density and calorific value, is another important factor in determining the efficiency of biomass pellets. Pellets with higher energy density are more efficient to transport and store, as they provide more energy per unit volume. In this study, waste rapeseed oil was found to significantly enhance the energy density of both grape pomace and corn cob pellets, making them more suitable for large-scale applications in energy production. Pellets made with 10% waste rapeseed oil exhibited the highest energy density, indicating their superior quality as biofuels.

Environmental Considerations: Emissions and Sustainability

The environmental impact of biomass combustion is a crucial consideration when evaluating the overall sustainability of biomass pellets. Biomass is often considered a cleaner alternative to fossil fuels, as it produces lower levels of carbon dioxide and other greenhouse gases. The use of waste oils, such as waste rapeseed oil, not only improves pellet performance but also contributes to reducing environmental pollution. By recycling waste oils, this method reduces the burden on landfills and helps divert potential pollutants from entering the environment.

Reducing Nitrogen Oxides (NOx) and Sulfur Oxides (SOx)

Nitrogen oxides (NOx) and sulfur oxides (SOx) are major air pollutants that contribute to smog and acid rain. The combustion of biomass pellets typically results in lower levels of these pollutants compared to fossil fuels. The addition of waste rapeseed oil further reduces the nitrogen and sulfur content in the pellets, leading to a decrease in the formation of NOx and SOx during combustion. Grape pomace pellets with 10% waste rapeseed oil, for example, exhibited nitrogen levels as low as 0.172%, making them a cleaner option for energy production.

Conclusion: Optimizing Biomass Pellet Production for Sustainable Energy

The production of biomass pellets from agricultural residues, such as grape pomace and corn cob, holds significant potential for sustainable energy generation. The addition of carefully selected additives, including sawdust, starch, and waste rapeseed oil, enhances the calorific value, combustion efficiency, and overall quality of the pellets. Among these, waste rapeseed oil proved to be the most effective additive, improving the energy density, reducing moisture and ash content, and contributing to cleaner combustion.

As global demand for renewable energy grows, optimizing biomass pellet production processes will play a critical role in meeting sustainability targets. The use of agricultural waste and waste oils as feedstocks for biomass pellets not only offers an eco-friendly solution to waste management but also enhances the energy efficiency of biomass as a renewable resource. Moving forward, the continued development of additives and pelletization technologies will be essential to further improve the performance of biomass pellets and increase their adoption in both residential and industrial energy applications.

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Reference

  1. Gheorghe, Daniela, and Ana Neacsu. "The influence of additives upon the energetic parameters and physicochemical properties of environmentally friendly biomass pellets." Journal of the Mexican Chemical Society 68.3 (2024): 438-454.

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