Understanding Biomass Pellet Combustion: A Comprehensive Study of Rice and Wheat Straws

Understanding Biomass Pellet Combustion: A Comprehensive Study of Rice and Wheat Straws

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Biomass combustion is a critical process in the field of renewable energy. As the world moves towards more sustainable and eco-friendly energy sources, biomass has become an increasingly important player due to its potential to reduce dependence on fossil fuels. Rice and wheat straws, two widely available agricultural residues, serve as effective biomass fuels due to their high energy content and biodegradability. The combustion of biomass pellets, made from these straws, is an essential area of study, especially when aiming to optimize energy extraction and reduce harmful emissions in combustion systems.

Biomass pellets, including those derived from rice and wheat straws, undergo complex physical and chemical transformations during combustion. Understanding the combustion behaviors of these materials under various conditions is pivotal to maximizing energy output, improving combustion efficiency, and minimizing environmental impact.

Wheat and rice straw stalks collected from fields, chopped straw stalks, powdered materials, and manufactured pellets.Fig 1. Bar graphs showing the evolution of pellet consumption for heating (A) and pellet production in Poland (B). (Drobniak A., et al., 2024)

Material Characteristics: Rice vs Wheat Straws

The combustion behavior of biomass pellets is highly dependent on the materials from which they are derived. Rice straw and wheat straw are both cellulose-rich materials but differ in their chemical composition, particle size, and structure, which affect their combustion characteristics.

Chemical Composition and Thermal Properties

Both rice and wheat straws contain volatile matter, fixed carbon, and ash, but their specific content varies. Wheat straw typically has a lower ash content, making it more desirable in terms of combustion efficiency. However, the higher potassium content in wheat straw leads to the formation of slag, which can decrease the lifespan of combustion equipment by causing deposits within furnaces. Rice straw, on the other hand, is rich in silica and sulfur, elements that can also contribute to ash deposition but generally at a slower rate.

Particle Size and Pelletization

Particle size plays a crucial role in the combustion efficiency of biomass pellets. The finer the particles, the more efficient the combustion process, as they have a larger surface area that is more readily exposed to the hot gases. Both rice and wheat straws were ground to fine particles before being pelletized into cylindrical shapes, with an average mass of around 5.1 grams for rice straw and 4.2 grams for wheat straw. The pelletization process helps to improve the handling, storage, and combustion properties of the biomass by compressing the material into a denser form.

Combustion Phases and Their Significance

The combustion process of biomass pellets involves three main phases: drying, devolatilization (volatile combustion), and char combustion. Each phase presents unique characteristics and challenges that affect the overall combustion efficiency.

  • Drying and Initial Heating
    When biomass pellets are introduced into a combustor, the first phase is the drying process, where moisture is evaporated from the material. During this phase, there is a rapid initial mass loss of about 10-20% of the pellet's original mass, mainly due to the release of water. At the same time, a small amount of volatile matter is also released, although the combustion process has not yet fully initiated.
  • Devolatilization (Volatile Combustion)
    The second phase, devolatilization, occurs when the temperature rises above 200°C. Here, the cellulose, hemicellulose, and lignin in the biomass begin to break down, releasing volatile gases such as carbon monoxide, methane, and various organic compounds. These gases combust in the presence of oxygen, contributing significantly to the heat release of the process. In both rice and wheat straws, this phase typically lasts between 100 and 300 seconds, depending on the temperature and the flow rate of air.
  • Char Combustion
    After the volatiles are consumed, the remaining solid material—char—undergoes a slower combustion process. This phase is characterized by the oxidation of the char, which produces carbon dioxide and additional heat. Char combustion is significantly slower than volatile combustion and often accounts for 20-30% of the total combustion time. The char's properties, including its porosity and composition, influence the rate of this phase.

Effect of Operating Conditions on Combustion

The combustion behavior of rice and wheat straw pellets is heavily influenced by the operating conditions within the combustor. Factors such as air temperature, flow rate, and pellet orientation all play vital roles in determining the efficiency of the combustion process.

Air Temperature

Increasing the air temperature in the combustor accelerates the combustion of both volatile matter and char. As the temperature rises from 350°C to 500°C, the ignition time for both rice and wheat straw pellets decreases, and the combustion process becomes faster overall. At higher temperatures, the chemical reactions involved in the pyrolysis and combustion stages occur more rapidly, leading to higher energy release in a shorter period. This also enhances the efficiency of heat transfer within the pellet.

Air Flow Rate

The flow rate of air entering the combustor also has a significant impact on combustion dynamics. Increased air flow rates improve the interaction between the pellet and the hot gas, facilitating more efficient heat transfer. This results in faster combustion times and higher peak temperatures. The study found that as the air flow rate increased from 64 kg/h to 83 kg/h, the ignition and combustion times decreased, and the maximum temperatures within the pellets rose.

Pellet Orientation

Pellet orientation inside the combustor affects the way hot gases interact with the pellet surface. Horizontal pellets (0°) have a larger surface area exposed to the hot air stream, which accelerates heat transfer and combustion. As the pellet is tilted at angles (30°, 45°, 60°, 90°), the exposure to the air changes, altering the combustion dynamics. Interestingly, the study showed that pellets positioned at a 45° angle experienced the most efficient combustion, likely due to the optimal exposure to the air flow and the resulting heat transfer.

Visual Analysis of Combustion Behavior

High-speed photography was employed to capture the combustion behavior of the pellets in real-time. These images provide valuable insights into the progression of combustion, from the initial ignition to the final char conversion.

  • Ignition and Volatile Combustion
    Upon ignition, both rice and wheat straw pellets emitted a bright luminosity as the volatile gases combusted. The rate of ignition was faster at higher air temperatures and flow rates. The combustion images revealed that rice straw pellets took longer to reach peak volatile combustion (around 300 seconds) compared to wheat straw (typically around 150-200 seconds).
  • Char Combustion
    During the char combustion phase, the intensity of the pellet's luminosity decreased, and dark patches began to appear on the pellet's surface as the char burned. These images allowed the researchers to pinpoint the exact moment of transition from volatile combustion to char combustion, highlighting the difference in combustion rates between the two materials.

Temperature and Mass Loss Histories

Temperature and mass loss profiles of both rice and wheat straw pellets were recorded to further understand the combustion process. These profiles reveal key insights into the behavior of the material as it undergoes various stages of combustion.

Temperature Profiles

The temperature profiles at the pellet surface and center were measured using thermocouples. It was observed that the surface temperature of the pellet increased rapidly during the volatile combustion phase, while the center temperature lagged slightly due to internal heat conduction. As the combustion process progressed, the temperature gradients between the surface and the center of the pellet narrowed.

Mass Loss Histories

The mass loss profiles demonstrated the distribution of volatile matter and char during combustion. Rice straw pellets exhibited a higher mass loss during the volatile combustion phase compared to wheat straw, indicating a faster release of volatiles. In contrast, the char combustion phase for wheat straw took longer, as the material retained more char for combustion compared to rice straw.

Conclusion

The combustion behavior of rice and wheat straw pellets is a complex process influenced by a variety of factors, including material properties, air temperature, flow rate, and pellet orientation. Understanding these factors and their interactions can lead to more efficient and environmentally friendly biomass combustion systems. Higher air temperatures and increased air flow rates accelerate the combustion process, but the orientation of the pellet plays a crucial role in optimizing heat transfer and combustion efficiency. Visual and thermal analysis further contribute to our understanding of the combustion phases and how the materials behave during each stage.

Ultimately, the findings of this study provide valuable insights for the development of more efficient biomass combustion systems, with applications ranging from domestic heating to industrial energy production. By improving the combustion characteristics of rice and wheat straws, we can enhance the sustainability of biomass as a renewable energy source.

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Reference

  1. El-Sayed, Saad A., et al. "Combustion and mass loss behavior and characteristics of a single biomass pellet positioning at different orientations in a fixed bed reactor." Biomass Conversion and Biorefinery 14.14 (2024): 15373-15393.

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