Upcycling Spent Engine Oil Into Advanced Grease: Formulation Innovation And Property MappingIf you are interested in products related to the research phase in this field, please contact for further inquiries.
In the industrial landscape, lubrication plays a critical role in ensuring machinery operates efficiently and reliably. Traditional lubricants, primarily mineral oil-based greases, have been the industry standard for decades. However, the environmental impact of these lubricants, particularly their disposal and the depletion of natural resources, has prompted a shift towards sustainable alternatives. One innovative solution gaining traction is the formulation of grease using waste engine oil (WEO) as the base fluid. This approach not only addresses environmental concerns but also offers economic benefits by recycling a hazardous waste material into a valuable product.
Fig 1. Effect of WEO content on FS greases' oil separation. (Hairunnaja M. A., et al., 2023)
The formulation of grease from waste engine oil begins with the selection of an appropriate base oil. WEO, after proper treatment to remove impurities, serves as an excellent base fluid due to its inherent lubricating properties. The next critical component is the thickener, which imparts the grease with its semi-solid consistency. Fumed silica (FS), known for its high surface energy and thickening effect, is a popular choice. FS particles form a three-dimensional network when dispersed in oil, enhancing the grease's stability and minimizing oil separation.
In addition to the base oil and thickener, various additives are incorporated into the grease formulation to enhance its performance. These additives may include anti-wear agents, corrosion inhibitors, and antioxidants. Molybdenum disulfide (MoS2), a common solid lubricant, is often added to improve the grease's high-pressure and high-temperature performance. The careful selection and blending of these additives are crucial for achieving the desired properties in the final grease product.

Consistency and Texture Analysis
The consistency of grease is a key performance parameter, influencing its ability to stay in place and provide continuous lubrication. The National Lubricating Grease Institute (NLGI) grade system is commonly used to classify grease consistency, ranging from NLGI 000 (very soft) to NLGI 6 (very hard). In the formulation of WEO-based grease, the ratio of WEO to thickener significantly impacts consistency. Higher WEO content results in softer grease, while increased thickener content yields firmer grease. Achieving the optimal balance is essential for meeting specific application requirements.

Oil Separation and Bleeding Tests
Oil separation and bleeding are critical factors affecting the performance and longevity of grease. Oil separation refers to the tendency of oil to separate from the grease matrix during storage, while oil bleeding is the controlled release of oil under mechanical stress. Both phenomena can lead to reduced lubrication effectiveness and increased wear. In WEO-based grease formulations, the type and concentration of thickener play a significant role in minimizing oil separation and bleeding. For instance, fumed silica's unique three-dimensional network structure effectively retains oil, reducing separation and bleeding.

Corrosion Resistance and FTIR Analysis
Corrosion resistance is another vital property of lubricating grease, particularly in applications involving metal surfaces. The formulated WEO-based grease must demonstrate low corrosiveness towards metal substrates, such as copper. Corrosion testing, following standards like ASTM D4048, evaluates the grease's ability to protect metal surfaces from degradation. Additionally, Fourier Transform Infrared (FTIR) spectroscopy is employed to analyze the chemical composition of the grease, detecting any impurities or contaminants that may affect its performance. FTIR analysis confirms the absence of harmful substances, ensuring the grease's suitability for various applications.
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Reference
This article is for research use only and cannot be used for any clinical purposes.